Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets.
نویسندگان
چکیده
Pyrene-intercalated layered compounds, [{Ru2(O2CCF3)4}2(TCNQR(x))]·2(pyrene) (TCNQR(x) = 7,7,8,8-tetracyano-p-quinodimethane derivatives; R(x) = H4 and F4), were synthesized. Pyrene prohibits intralayer electron transfer of [Ru2(II,II)] → TCNQR(x), even in the compound with R(x) = F4, from occurring.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 45 شماره
صفحات -
تاریخ انتشار 2013